拉伸工艺对渔用聚乙烯纤维结构与性能的影响
Effect of draw process on the structure and properties of fishery polyethylene fibers
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摘要: 为纺制高性能渔用聚乙烯纤维,实验以齐鲁石化生产的高密度聚乙烯为原料,进行螺杆挤出机熔融纺丝—多级热拉伸纺丝实验。结果显示,一级拉伸倍数为8.17倍时,聚乙烯纤维的断裂强度和结节强度分别为5.71和4.56 cN/dtex;当采用二级拉伸工艺,一级拉伸倍数8.17倍,总拉伸倍数为9.52倍时,所制备的渔用聚乙烯纤维的断裂强度和结节强度分别为7.91和5.24 cN/dtex,比现行国家标准中规定的聚乙烯单丝优等品指标高出41.3%和34.4%。研究表明,二级拉伸工艺可使聚乙烯大分子链在纤维中的排列更加规整,提高大分子链的取向度,制备的渔用聚乙烯纤维的综合渔用性能更好。随着总拉伸倍数的提高,聚乙烯纤维的断裂强度、声速取向和热性能均显著提高。随拉伸倍数提高,渔用聚乙烯纤维的结节强度呈现先升高后降低的趋势。Abstract: High density polyethylene produced by Qilu Petrochemical Engineering Co.Ltd was melt-spun by screw extruder and then multi-step drawn at high temperature to fabricate high performance fishery PE fibers.It was showed that when the draw ratio was 8.17 in the one-step process,the breaking strength and knot strength of the PE fiber were 5.71cN/dtex and 4.56cN/dtex,respectively; but when the first and total draw ratio were 8.17 and 9.52 in the two-step process,the breaking strength and knot strength were 7.91cN/dtex and 5.24cN/dtex,which were 41.3% and 34.4% higher than the high-class products specified in the national standard,respectively.It was found that the PE fibers fabricated by two-step process showed more regular macromolecular chains,higher orientation and better fishery properties than those fabricated by one-step process.In addition,with the total draw ratio increased,the breaking strength,sound orientation and thermal properties were improved,but the knot strength increased first and subsequently decreased.
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